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I need help with Unknown Solid Tests - ( Chemistry )

How can you tell that which is in each tube. Any tests can be performed.  

1. NaCl   or  NaNO3

2. CaSO4  or  CaCO3

3. Mg(OH)2  or  MgSO4

4. Na2HPO4  or  NaHCO3

5. NH4NO3  or  KNO3

6. Zn(C2H3O2)2  or  Zn(NO3)2

7. ZnSO4  or  MgSO4

8. CaCl2  or  FeSO4

9. Zn(C2H3O2)2  or  NH4C2H3O2

10. CoCl2  or  KBr

11. KCl  or  KI

12. Na2SO3  or  Na2SO4

13. NaCl  or  AlCl3.6H2O

14. NaHSO4  or  Na2SO4


โดย:  Hi   [5 ก.พ. 2559 01:35]
ข้อคิดเห็นจากผู้ทรงคุณวุฒิจะแสดงในกรอบสีเขียว ส่วนข้อคิดเห็นหรือความเห็นจากผู้อื่นจะแสดงในกรอบปกติ
ข้อคิดเห็นที่ 1:1

1. NaCl  or  NaNO3
Dissolve the solid in water . Test with AgNO3 Solution
NaCl (aq) + AgNO3 (aq) --- > AgCl ( white precipitate ) + NaNO3 (aq)
NaNO3 (aq) + AgNO3 (aq) --- > No Reaction

2. CaSO4  or  CaCO3
Test with HCl Solution
CaSO4 (s) + 2 HCl (aq) --- > No reaction ; CaSO4 will slightly dissolve in the HCl Solution
CaCO3 (s) + 2 HCl (aq) --- > CaCl2 (aq) + H2O + CO2 ( gas ) ___ Dissolution of Solid with Evolution of Gas

3. Mg(OH)2  or  MgSO4
Test for solubility in water
Mg(OH)2 is insoluble in water ;
MgSO4 is soluble in water

4. Na2HPO4  or  NaHCO3
Test with HCl Solution
Na2HPO4 (s) + HCl (aq) --- > Dissolution of Solid ; No gas generated
2 NaHCO3 (s) + 2 HCl (aq) --- > 2 NaCl (aq) + H2O + CO2 ( gas ) ___ Dissolution of Solid with Evolution of Gas

5. NH4NO3  or  KNO3
Test with NaOH Solution
NH4NO3 (s) + NaOH (aq) --- > NaNO3 (aq) + NH3 ( gas which can turn moist Red litmus paper to Blue )
KNO3 (s) + NaOH (aq) --- > No reaction ; KNO3 will just dissolve

6. Zn(C2H3O2)2  or  Zn(NO3)2
Adding dilute sulfuric acid
Zn(C2H3O2)2 (s) + H2SO4 (aq) --- > ZnSO4 (aq) + 2 CH3COOH (aq) __ Vinegar odor
Or test for Nitrate ( as oxidizing agent )
Zn(NO3)2 (s) + H2SO4 (aq) + KI (aq) --- > ZnSO4 (aq) + NO (g) + I2 ( aq ; brown color ) ____ equation not balanced
2 NO (g) + O2 --- > 2 NO2 ( Reddish-Brown Gas )

7. ZnSO4  or  MgSO4
Test with NaOH solution
ZnSO4 >> Gel-Like Precipitate ; soluble in excess NaOH
ZnSO4 (aq) + 2 NaOH (aq) --- > Zn(OH)2 (s) + 2 Na^+ (aq) + SO4^2- (aq)
Zn(OH)2 (s) + 2 NaOH (aq) --- > Zn(OH)4^2- (aq) + 2 Na^+ (aq)
MgSO4 >> Gel-Like Precipitate ; insoluble in excess NaOH
MgSO4 (aq) + 2 NaOH (aq) --- > Mg(OH)2 (s) + 2 Na^+ (aq) + SO4^2- (aq)

8. CaCl2  or  FeSO4
Dissolve the solid in water . Test with BaCl2 solution
CaCl2 (aq) + BaCl2 (aq ) >> no reaction
FeSO4 (aq) + BaCl2 (aq) --- > BaSO4 (s) + Fe^2+ (aq) + 2 Cl^- (aq)
White Precipitate of BaSO4 ; insoluble in HCl
[ Actually , CaCl2 is a white solid ; FeSO4 is a green solid . You can differentiate by just visual inspection ]

9. Zn(C2H3O2)2  or  NH4C2H3O2
Dissolve the solid in water . Test with NaOH solution
Zn(C2H3O2)2 (aq) + 2 NaOH (aq) --- > Zn(OH)2 (s) + 2 Na^+ (aq) + 2 C2H3O2^- (aq)
Zn(OH)2 (s) + 2 NaOH (aq) --- > Zn(OH)4^2- (aq) + 2 Na^+ (aq)
[ Zn(OH)2 precipitates and then dissolves in Excess NaOH
NH4C2H3O2 (aq) + NaOH (aq) --- > NaC2H3O2 (aq) + NH3 ( gas which can turn moist Red litmus paper to Blue )

10. CoCl2  or  KBr
Dissolve the solid in water . Test with concentrate HCl solution
Co(H2O)6^2+ ( aq ; faint pink ) + 4 Cl^- (aq) --- > CoCl4^2- ( aq ; Blue Color ) + 6 H2O
KBr (aq) + HCl (aq) --- > No reaction

11. KCl  or  KI
Dissolve the solid in water . Test with CuSO4 solution
CuSO4 (aq) + KCl (aq) --- > No reaction
CuSO4 (aq) + 2 KI (aq) --- > CuI (s) + K2SO4 (aq) + I2 ( aq ; brown solution )
CuI is Copper (I) iodide

12. Na2SO3  or  Na2SO4
Dissolve the solid in water . Test with Iodine solution
Na2SO3 (aq) + I2 ( aq ; brown solution ) + H2O --- > Na2SO4 (aq) + 2 HI (aq) ___ Colorless Solution
Na2SO4 (aq) + I2 ( aq ; brown solution ) --- > No reaction

13. NaCl  or  AlCl3.6H2O
Dissolve the solid in water . Test with NaOH solution
NaCl >> No reaction
AlCl3 >> Gel-Like Precipitate ; soluble in excess NaOH
AlCl3 (aq) + 3 NaOH (aq) --- > Al(OH)3 (s) + 3 Na^+ (aq) + 3 Cl^- (aq)
Al(OH)3 (s) + NaOH (aq) --- > Al(OH)4^- (aq) + Na^+ (aq)

14. NaHSO4  or  Na2SO4
Dissolve the solid in water . Add “ Methyl Orange Indicator Solution “
NaHSO4 (aq) is acidic solution >> Red Color Solution
Na2SO4 (aq) is neutral solution >> Yellow Color Solution

โดย:  Real Chemist  [5 ก.พ. 2559 01:38]
หากท่านต้องการถามคำถามที่ไม่เกี่ยวข้องกับหัวข้อคำถามนี้ กรุณากดปุ่มนี้

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