Safety data sheet
According to EC Directive 91/155/EEC
MERCK Schuchardt
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1. Identification of the substance/preparation and of the company/undertaking
Identification of the product
Catalogue No.: 821874
Product name: Bis(2-ethylhexyl) phthalate for synthesis

Manufacturer/supplier identification
Company: Merck Ltd.
9th Floor, Monterey Tower, 2170 New Petchburi Road, Bangkapi, Huaykwang, Bangkok 10320
Tel: (662) 308 - 0218

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2. Composition/information on ingredients
Synonyms
Diisooctyl phthalate ; Phthalic acid bis(2-ethylhexyl) ester ; Di(2-ethylhexyl) phthalate ; DOP

CAS-No.: 117-81-7 EC-Index-No.: -
Molar mass: 390.57 EINECS-No.: 204-211-0
Molecular formula: C24H38O4

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3. Hazards identification
Possible risk of impaired fertility. Possible risk of harm to the unborn child.

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4. First aid measures
Eye and skin contact: rinse out with water. Remove contaminated clothing. After inhalation: fresh air.
After swallowing: make the victim drink plenty of water, induce vomiting. Consult doctor if feeling unwell.

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5. Fire-fighting measures
Suitable extinguishing media:
CO2 , foam , powder

Special risks:
Combustible. Vapours heavier than air.

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6. Accidental release measures
Take up with liquid-absorbent material (e.g. Chemizorb® ). Forward for disposal. Clean up affected area.

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7. Handling and storage
Handling:
No further requirements.

Storage:
tightly closed , in a well-ventilated place , away from combustible substances

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8. Exposure controls/personal protection
Specific control parameter
MAK Germany (max. workplace conc.)
Di(2-ethylhexyl) phthalate 10 mg/m3

Personal protective equipment:
Respiratory protection: required when vapours/aerosols are generated.
Eye protection: required
Hand protection: required
Industrial hygiene: Change contaminated clothing. Wash hands and face after working with substance.

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9. Physical and chemical properties
Form: liquid
Colour: colourless
Odour: pleasant
pH value ( ) 7
Viscosity dynamic (20 °C) 78 mPa*s
Melting temperature -45 °C
Boiling temperature 385 °C
Ignition temperature 350 °C
Flash point 195 °C
Explosion limits lower 0.1 Vol%
upper 0.2 Vol%
Vapour pressure (150 °C) 0.09 hPa
Density (20 °C) 0.98 g/cm3
Solubility in water (20 °C) 0.1 g/l
organic solvents (20 °C) soluble

Further information
Distillable in an undecomposed state at normal pressure.

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10. Stability and reactivity
no information available

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11. Toxicological information
Acute toxicity
LD50 (oral, rat): 30600 mg/kg
LD50 (dermal, rabbit): 25000 mg/kg

Further toxicological information
Very low acute toxicity in animal experiments. When vapours/aerosols are generated:
After skin contact: Irritations.
After eye contact: Irritations.
After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.


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12. Ecological information
No ecological problems are to be expected when the product is handled and used with due care and attention.

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13. Disposal considerations
Product:
There are no uniform EC Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste.

Packaging:
Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminated packaging may be treated like household waste or recycled.

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14. Transport information
Not subject to transport regulations.

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15. Regulatory information
Labelling according to EC Directives
Symbol: Xn Harmful immediately and show this container or label.
R-phrases: R 62-63 Possible risk of impaired fertility. Possible risk of harm to the unborn child.
S-phrases: S 36/37 Wear suitable protective clothing and gloves.
EC-No.: 204-211-0 EC label

German regulations
Water pollution class 1 (slightly polluting substance)

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16. Other information
no information available


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