Safety data sheet
According to EC Directive 91/155/EEC
MERCK Schuchardt
====================
1. Identification of the substance/preparation and of the company/undertaking
Identification of the product
Catalogue No.: 823300
Product name: Propene for synthesis

Manufacturer/supplier identification
Company: Merck Ltd.
9th Floor, Monterey Tower, 2170 New Petchburi Road, Bangkapi, Huaykwang, Bangkok 10320
Tel: (662) 308 - 0218

====================
2. Composition/information on ingredients
Synonyms
Propylene

CAS-No.: 115-07-1 EC-Index-No.: 601-011-00-9
Molar mass: 42.08 EINECS-No.: 204-062-1
Molecular formula: C3H6

====================
3. Hazards identification
Extremely flammable.

====================
4. First aid measures
After inhalation: fresh air. If necessary, apply mouth-to-mouth resuscitation or mechanical ventilation. If victim is unconscious: lateral recumbent position.

====================
5. Fire-fighting measures
Suitable extinguishing media:
powder , CO2 , Cool containers with water.

Special risks:
Combustible. Formation of explosive mixtures possible with air. Keep away from sources of ignition. Beware of backfiring.

====================
6. Accidental release measures
Stop flow of gas, move leaking cylinder to open air if without risk. Do not inhale vapours.

====================
7. Handling and storage
Handling:
No further requirements.

Storage:
tightly closed , cool Take measures to prevent electrostatic charging.

====================
8. Exposure controls/personal protection
Personal protective equipment:
Respiratory protection: required
Eye protection: required
Hand protection: required
Industrial hygiene: Change contaminated clothing. Application of skin-protective barrier cream recommended. Wash hands after working with substance.

====================
9. Physical and chemical properties
Form: gas
Colour: colourless
Odour: almost odourless
pH value not available
Melting temperature -185 °C
Boiling temperature -48 °C
Ignition temperature 455 °C
Flash point not available
Explosion limits lower 2 Vol%
upper 11.7 Vol%
Vapour pressure (20 °C) 9600 hPa

====================
10. Stability and reactivity
Conditions to be avoided
no information available

Substances to be avoided
strong oxidizing agent

Hazardous decomposition products
no information available

====================
11. Toxicological information
Acute toxicity
Quantitative data on the toxicity of this product are not available.

Further toxicological information
The literature and our own experience have not revealed any hazardous properties. After uptake of large quantities: Drowziness, dizziness, euphoria, excitation, spasms, in certain circumstances narcosis.

====================
12. Ecological information
No ecological problems are to be expected when the product is handled and used with due care and attention.

====================
13. Disposal considerations
Product:
There are no uniform EC Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste.

Packaging:
Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminated packaging may be treated like household waste or recycled.

====================
14. Transport information
Transport over land ADR/RID and GGVS/GGVE (Germany)
GGVS/GGVE class: 2 Number and letter:
ADR/RID class: 2 Number and letter:
Name of material: 1077 PROPEN

River transport ADN/ADNR
not examined

Sea transport IMDG
IMDG class: 2.1 UN-No.: 1077 Packaging group:
Ems: 2-07 MFAG: 310
Correct technical name: PROPYLENE

Air transport ICAO-TI and IATA-DGR
ICAO/IATA class: 2.1 UN/ID-No.: 1077 Packaging group:
Correct technical name: PROPYLENE

The transport regulations are cited according to international regulations and in the form applicable in Germany (GGVS/GGVE). Possible national deviations in other countries are not considered.

====================
15. Regulatory information
Labelling according to EC Directives
Symbol: F+ Extremely flammable immediately and show this container or label.
R-phrases: R 12 Extremely flammable.
S-phrases: S 9-16-33 Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.
EC-No.: 204-062-1 EC label

German regulations
Water pollution class 0 (generally nonpolluting substance)

====================
16. Other information
no information available


====================