| Safety data sheet |
| According to EC Directive 91/155/EEC |
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| 1. Identification of the substance/preparation and of the company/undertaking |
| Identification of the product | ||
| Catalogue No.: | 106437 | |
| Product name: | Sodium cyanide pure | |
| Manufacturer/supplier identification | ||
| Company: |
Merck Ltd. 9th Floor, Monterey Tower, 2170 New Petchburi Road, Bangkapi, Huaykwang, Bangkok 10320 Tel: (662) 308 - 0218 |
|
| 2. Composition/information on ingredients |
| CAS-No.: | 143-33-9 | EC-Index-No.: | 006-007-00-5 | ||
| Molar mass: | 49.01 | EINECS-No.: | 205-599-4 | ||
| Molecular formula: | NaCN | ||||
| 3. Hazards identification |
| Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. |
| 4. First aid measures |
|
General information: Rapid action is called for. First-aid personnel: ensure self-protection! Immediately summon doctor (mentioning hydrocyanic acid poisoning). If breathing stops: immediately apply mechanical ventilation, if necessary also oxygen. After skin contact: wash off with plenty of water. Remove contaminated clothing. After eye contact: rinse out with plenty of water with the eyelid held wide open. After swallowing: if victim is still conscious, make him drink plenty of water, induce vomiting, administer activated charcoal (20 - 40 g in 10% slurry). Immediately summon doctor. Instructions for the doctor: Keep antidotes ready ( sodium thiosulfate , dimethylaminophenol , Cobalt-EDTA ) |
| 5. Fire-fighting measures |
| Suitable extinguishing media: |
| CO2, powder. Fire extinguisher: powder , carbon dioxide |
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Extinguishing media not to be used: |
| water |
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Special risks: |
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Non-combustible. Development of hazardous combustion gases or vapours possible in the event of fire. Do not allow product to come into contact with water. The following may develop in event of fire: hydrogen cyanide |
| 6. Accidental release measures |
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Person-related precautionary measures: Avoid inhalation of dusts in all circumstances. Environmental-protection measures: Do not allow to enter sewerage system. Procedures for cleaning / absorption: Carefully take up dry. Forward for disposal. Clean up affected area. |
| 7. Handling and storage |
| Handling: |
| No further requirements. |
| Storage: |
|
Tightly closed. Dry. In a well-ventilated place. At +15°C to +25°C. Accessible only for authorized persons. Requirements for storage rooms and containers: No metal containers. |
| 8. Exposure controls/personal protection |
| Specific control parameter | ||
| MAK Germany (max. workplace conc.) | ||
| Cyanides (as CN) | 5 mg/m3 | |
| Personal protective equipment: | |
| Respiratory protection: | required |
| Eye protection: | required |
| Hand protection: | required |
| Industrial hygiene: | Immediately change contaminated clothing. Apply skin- protective barrier cream. Wash hands and face after working with substance. |
| 9. Physical and chemical properties |
| Form: | solid | |||
| Colour: | white | |||
| Odour: | bitter almond-like | |||
| pH value | ||||
| at 100 g/l water | (20 °C) | »ÃÐÁÒ³ 11.7 | ||
| Melting temperature | 563 °C | |||
| Boiling temperature | 1496 °C | |||
| Ignition temperature | not available | |||
| Flash point | not available | |||
| Explosion limits | lower | not available | ||
| upper | not available | |||
| Vapour pressure | (20 °C) | 1.013 mbar | ||
| Density | (20 °C) | 1.55 g/cm3 | ||
| Solubility in | water | (20 °C) | 600 g/l | |
| ethanol | (20 °C) | sparingly soluble | ||
| Thermal decomposition | > 1500 °C |
| 10. Stability and reactivity |
| Conditions to be avoided |
| no information available |
| Substances to be avoided |
| acids , water , oxidizing agent , alkali salts , chlorates , nitrites , nitrates , carbon dioxide |
| Hazardous decomposition products |
| hydrogen cyanide |
| Further information |
| sensitive to moisture ; hygroscopic |
| 11. Toxicological information |
| Acute toxicity |
| LD50 (oral, rat): 10 mg/kg |
| Further toxicological information |
|
After eye contact: irritant effect After inhalation: dyspnoea , mucosal irritations , absorption After skin contact: absorption Lethal effect after absorption. Decomposition of the substance with tissue moisture. Effect of the decomposition products. Highly toxic. After swallowing: nausea , vomiting , absorption Systemic effects: dyspnoea , respiratory paralysis , unconsciousness , cardiovascular disorders The following applies to cyanogen compounds/ nitriles in general: utmost caution! Release of hydrocyanic acid is possible - blockade of cellular respiration. Cardiovascular disorders, dyspnoea, unconsciousness. |
| 12. Ecological information |
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Behavior in environmental compartments: Evaluation number (FRG) (mammal): 5.0 ; Evaluation number (FRG) (bacteria): 6.0 ; Evaluation number (FRG) (fish): 3.2 ; Ecotoxic effects: Biological effects: Toxic for aquatic organisms Fish toxicity: L.idus LC0: 0.04 mg/l ; L.idus LC50: 0.07 mg/l ; L.idus LC100: 0.12 mg/l ; Protozoa : E.sulcatum EC0: 1.8 mg/l ; Daphnia toxicity: Daphnia EC0: 3.4 mg/l Hazard for drinking water supplies. High aquatic toxicity. Forms toxic mixtures in water, dilution measures notwithstanding. Reacts with water to form toxic decomposition products. Further ecologic data: Do not allow to enter waters, waste water, or soil! |
| 13. Disposal considerations |
| Product: |
| There are no uniform EC Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste. |
| Packaging: |
| Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminated packaging may be treated like household waste or recycled. |
| 14. Transport information |
| Transport over land ADR/RID and GGVS/GGVE (Germany) | ||||
| GGVS/GGVE class: | 6.1 | Number and letter: | 41a | |
| ADR/RID class: | 6.1 | Number and letter: | 41a | |
| Name of material: | 1689 NATRIUMCYANID | |||
| River transport ADN/ADNR | |||
| not examined | |||
| Sea transport IMDG | ||||||
| IMDG class: | 6.1 | UN-No.: | 1689 | Packaging group: | I | |
| Ems: | 6.1-04 | MFAG: | 215 | |||
| Correct technical name: | SODIUM CYANIDE, SOLID - MARINE POLLUTANT | |||||
| Air transport ICAO-TI and IATA-DGR | |||||
| ICAO/IATA class: | 6.1 | UN/ID-No.: | 1689 | Packaging group: | I |
| Correct technical name: | SODIUM CYANIDE | ||||
| The transport regulations are cited according to international regulations and in the form applicable in Germany (GGVS/GGVE). Possible national deviations in other countries are not considered. |
| 15. Regulatory information |
| Labelling according to EC Directives | ||
| Symbol: | T+ | Very toxic immediately and show this container or label. |
| R-phrases: | R 26/27/28-32 | Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. |
| S-phrases: | S 1/2-7-28.1-29-45 | Keep locked up and out of reach of children. Keep container tightly closed. After contact with skin, wash immediately with plenty of water. Do not empty into drains. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
| EC-No.: | 205-599-4 | EC label |
| German regulations | ||
| Water pollution class | 3 | (highly polluting substance) |
| 16. Other information |
| Reason for alteration |
| General update. |
