Potassium dichromate, volumetric standard secondary reference material for redox titration, traced back to NIST Standard Reference Material (SMR)
Potassium bichromate ; Potassium pyrochromate
MERCK
Xi
CAS :7778-50-9
Do not allow to enter sewerage system
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Hazard / Symptom
Hazard Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact.
After inhalation absorption. Burns in mucous membranes. Damage to nasal mucosa (possibly perforation of the septum). Irritations in the upper airways.
After skin contact being a strong oxidant, the substance can cause burns and ulcerations. Poor tendency for ulcers to heal following penetration of substance into the wound.
After eye contact burns.
After swallowing burns. Severe symptoms in the gastrointestinal tract, such as bloody diarrhoea, vomiting (aspiration pneumonia!), spasms, unconsciousness, circulatory collapse.
Systemic effects after absorption formation of methaemoglbinaemia, damage to liver and kidneys may occur.
Further data in susceptible persons the substance rapidly leads to sensitisation and allergic reactions of the airways (risk of pneumonia !).
Additional informations Inhalable chromium(VI) compounds have proved to be definitely carcinogenic in animal experiments.
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Protective equipments / General working measures
GLASS GLOVE RESPIRATOR
NO SMOKING
Do not breathe dust. After contact with skin, wash immediately with plenty of .
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Accidental release measures / Fire-fighting measures
Person-related precautionary measures Avoid inhalation of dusts in all circumstances. Avoid substance contact.
Procedures for cleaning / absorption Carefully take up dry. Forward for disposal. Clean up affected area. Avoid generation of dusts.
Suitable extinguishing media Water, foam.
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First aid
FIRST AID
After inhalation fresh air.
After skin contact wash off with plenty of water. Remove contaminated clothing.
After eye contact rinse out with plenty of water with the eyelid held wide open. Summon eye specialist.
After swallowing make victim drink plenty of water, induce vomiting, summon doctor.
Additional informations General information: Carefully clean wounds and cover with sterile dressing material.
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