ACRYLONITRILE, STAB.
Synonym:
  Synonyms * Acritet * Acrylnitril (German, Dutch) * Acrylon * Acrylonitrile (ACGIH:OSHA) * Acrylonitrile monomer * Akrylonitril (Czech) * Akrylonitryl (Polish) * Carbacryl * Cianuro di vinile (Italian) * Cyanoethylene * Cyanure de vinyle (French) * ENT 54 * Fumigrain * Miller's fumigrain * Nitrile acrilico (Italian) * Nitrile acrylique (French) * Propenenitrile * 2-Propenenitrile * RCRA waste number U009 * TL 314 * VCN * Ventox * Vinyl cyanide * Vinylcyanide (OSHA) * Vinylkyanid (Czech)
CAS Number : 107-13-1
HAZARD (GHS)
EXPOSURE CONTROLS/PERSONAL PROTECTION
Highly flammable liquid and vapour / Toxic if swallowed / Fetal if contact with skin / Fetal if swallowed / Cause skin irritation / Cause serious eye irritation / May cause an allergic skin reaction / Suspected of causing genetic defects / Suspected of causing cancer / Suspected of damaging fertility or the unborn child / Cause damage to organ (nervous system, liver, respiratory, hematopoietic system, testis, kidney) / May cause respiratory irritation; or may cause drowsiness or dizziness / Toxic to aquatic life
ENGINEERING CONTROLS
     Safety shower and eye bath.  Use nonsparking tools.  Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
     Wash contaminated clothing before reuse.  Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection:  Government approved respirator.
     Hand Protection:  Compatible chemical-resistant gloves.
     Eye Protection:  Chemical safety goggles.
HANDLING
     Directions for Safe Handling:  Do not breathe vapor.  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Keep away from heat, sparks, and open flame.
SPECIAL REQUIREMENTS:
     Heat and light sensitive.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.  Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Cover with dry-lime, sand, or soda ash.  Place in covered containers using non-sparking tools and transport outdoors.  Ventilate area and wash spill site after material pickup is complete.
EXTINGUISHING MEDIA
     Suitable:  Water spray.  Carbon dioxide, dry chemical powder, or appropriate foam.
SPECIAL RISKS
     Specific Hazard(s):  Flammable liquid.  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Vapor may travel considerable distance to source of ignition and flash back.  Container explosion may occur under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
     In case of skin contact, flush with copious amounts of water for at least 15 minutes.  Remove contaminated clothing and shoes.  Call a physician.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.  Assure adequate flushing by separating the eyelids with fingers.  Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician immediately.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #01710

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