Safety Guideline

BROMINE, 99.99+%

Synonym:

Synonyms * Brom (German) * Brome (French) * Bromine (ACGIH:OSHA) * Bromo (Italian) * Broom (Dutch) * Dibromine

CAS Number : 7726-95-6

HAZARD (GHS)

EXPOSURE CONTROLS/PERSONAL PROTECTION

May be corrosive to metal / Toxic if swallowed / Fetal if swallowed / cause sever skin burn and eye damage / Cause serious eye damage / Cause damage to organ (respiratory system, central nervous system, nervous system, endocrine system) / Very toxic to aquatic life / very toxic to aquatic life with long lasting effects

ENGINEERING CONTROLS
     Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
     Wash thoroughly after handling. Remove and wash contaminated clothing promptly.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection: Self-contained breathing apparatus should be worn Eye Protection: Use safety shield.
     Special Protective Measures: Impervious protective clothing.

HANDLING
     Directions for Safe Handling: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Handle bromine only with equipment made of Kynar, Teflon, monel, Pyrex glass, and lead-lined steel.
STORAGE
     Conditions of Storage: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place.
     Unsuitable: Do not store in polyethylene containers.
SPECIAL REQUIREMENTS:
     May develop pressure. Open carefully.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area and keep personnel upwind.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete.

EXTINGUISHING MEDIA
     Suitable: Noncombustible. Use water spray to cool fire-exposed containers.
SPECIAL RISKS
     Specific Hazard(s): Emits toxic fumes under fire conditions. Contact with other material may cause fire. May accelerate combustion.
     Explosion Hazards: Container explosion may occur under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
CONDITIONS OF FLAMMABILITY
     Vigorously supports combustion.

AFTER INHALATION
     If inhaled, remove to fresh air. If breathing becomes difficult, call a physician.
AFTER SKIN CONTACT
     In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious. Call a physician.

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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #328138

The information contained herein is based on data considered accurate.
However,no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof.
Thailand Research Fund/Chulalongkorn University assume no responsibility for personal injury or property damage to users or third parties caused by the material.
Such users assume all risks associated with the use of the material.