HYDRAZINE, ANHYDROUS, 98%
Synonym:
  Synonyms * Hydrazine (ACGIH:OSHA) * Hydrazyna (Polish) * Levoxine * Nitrogen hydride * Oxytreat 35 * RCRA waste number U133
CAS Number : 302-01-2
HAZARD (GHS)
EXPOSURE CONTROLS/PERSONAL PROTECTION
Flammable liquid and vapour / Toxic if swallowed / Fetal if contact with skin / Cause serious eye damage / May cause an allergic skin reaction / Suspected of causing genetic defects / Suspected of causing cancer / Suspected of damaging fertility or the unborn child / Cause damage to organ (liver, respiratory, kidney, adrenal, nervous system) / May cause respiratory irritation; or may cause drowsiness or dizziness / Very toxic to aquatic life / very toxic to aquatic life with long lasting effects
ENGINEERING CONTROLS
     Safety shower and eye bath.  Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
     Wash contaminated clothing before reuse.  Discard contaminated shoes.  Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection:  Government approved respirator.
     Hand Protection:  Compatible chemical-resistant gloves.
     Eye Protection:  Chemical safety goggles.
     Special Protective Measures:  Faceshield (8-inch minimum).
HANDLING
     Directions for Safe Handling:  Do not breathe vapor.  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Keep away from heat and open flame.  Store in a cool dry place.
SPECIAL REQUIREMENTS:
     Handle and store under inert gas.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Cover with dry lime or soda ash, pick up, keep in a closed container, and hold for waste disposal.  Ventilate area and wash spill site after material pickup is complete.
EXTINGUISHING MEDIA
     Suitable:  Carbon dioxide.
SPECIAL RISKS
     Specific Hazard(s):  Combustible liquid.  Emits toxic fumes under fire conditions.
     Explosion Hazards:  May explode when heated.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
CONDITIONS OF FLAMMABILITY
     Warning:  hydrazine vapor in air is flammable at 4.7 to 100% hydrazine by volume - handle under nitrogen!  Some metals and alloys including monel, bronze, brass, cadmium, gold, molybdenum, and stainless steel with more than 0.5% molybdenum or rust cause decomposition of hydrazine
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
     In case of skin contact, flush with copious amounts of water for at least 15 minutes.  Remove contaminated clothing and shoes.  Call a physician.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.  Assure adequate flushing by separating the eyelids with fingers.  Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician.  Do not induce vomiting.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #215155

The information contained herein is based on data considered accurate.
However,no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof.
Thailand Research Fund/Chulalongkorn University assume no responsibility for personal injury or property damage to users or third parties caused by the material.
Such users assume all risks associated with the use of the material.