HAZARD (UN) |
EXPOSURE CONTROLS/PERSONAL PROTECTION |
Xn |
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Harmful. SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Flammable. Harmful by inhalation and in contact with skin. Irritating to skin. |
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ENGINEERING CONTROLS Safety shower and eye bath. Use nonsparking tools. Mechanical exhaust required. GENERAL HYGIENE MEASURES Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Government approved respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. |
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HANDLING Directions for Safe Handling: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Handle and store under nitrogen. |
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PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with an activated carbon adsorbent, take up and place in closed containers. Transport outdoors. Ventilate area and wash spill site after material pickup is complete. |
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EXTINGUISHING MEDIA Suitable: Carbon dioxide, dry chemical powder, or appropriate foam. Unsuitable: Water may be effective for cooling, but may not effect extinguishment. SPECIAL RISKS Specific Hazard(s): Vapor may travel considerable distance to source of ignition and flash back. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SPECIFIC METHOD(S) OF FIRE FIGHTING Use water spray to cool fire-exposed containers. |
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AFTER INHALATION If inhaled, remove to fresh air. If breathing becomes difficult, call a physician. AFTER SKIN CONTACT In case of contact, immediately wash skin with soap and copious amounts of water. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. |