BENZYL CHLORIDE
Synonym:
  Synonyms * Benzene, (chloromethyl)- * Benzile (cloruro di) (Italian) * Benzyl chloride (ACGIH:OSHA) * Benzyle (chlorure de) (French) * Benzylchlorid (German) * Chloromethylbenzene * Chlorophenylmethane * alpha-Chlorotoluene * omega-Chlorotoluene * alpha-Chlortoluol (German) * Chlorure de benzyle (French) * NCI-C06360 * RCRA waste number P028 * Tolyl chloride
CAS Number : 100-44-7
HAZARD (GHS)
EXPOSURE CONTROLS/PERSONAL PROTECTION
Combustible liquid / Harmful if swallowed / Fetal if swallowed / Cause serious eye damage / May cause an allergic skin reaction / Suspected of causing cancer / Suspected of damaging fertility or the unborn child / Cause damage to organ (nervous system, respiratory) / May cause damage to organs (heart, liver, thyroid gland) / Very toxic to aquatic life
ENGINEERING CONTROLS
     Use only in a chemical fume hood.  Safety shower and eye bath.
GENERAL HYGIENE MEASURES
     Wash contaminated clothing before reuse.  Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection:  Government approved respirator in nonventilated areas and/or for exposure above the TLV or PEL.
     Hand Protection:  Compatible chemical-resistant gloves.
     Eye Protection:  Chemical safety goggles.
HANDLING
     Directions for Safe Handling:  Do not breathe vapor.  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Keep away from heat and open flame.  Store in a cool dry place.
SPECIAL REQUIREMENTS:
     Moisture sensitive.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.  Wear disposable coveralls and discard them after use.
METHODS FOR CLEANING UP
     Absorb on sand or vermiculite and place in closed containers for disposal.  Ventilate area and wash spill site after material pickup is complete.
EXTINGUISHING MEDIA
     Suitable:  Carbon dioxide, dry chemical powder, or appropriate foam.
     Unsuitable:  Do not use water.
SPECIAL RISKS
     Specific Hazard(s):  Combustible liquid.  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Stabilized and unstabilized benzyl chloride will undergo a rapid, exothermic polymerization reaction above 212?F (100?C).  This reaction occurs at much lower temperatures when species of iron are present.  The gases generated during rapid polymerization will result in rapid build-up of dangerous pressure in closed vessels
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
CONDITIONS OF FLAMMABILITY
     Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas.
AFTER INHALATION
     If inhaled, remove to fresh air.  If breathing becomes difficult, call a physician.
AFTER SKIN CONTACT
     In case of contact, immediately wash skin with soap and copious amounts of water.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.  Assure adequate flushing by separating the eyelids with fingers.  Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #13270

The information contained herein is based on data considered accurate.
However,no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof.
Thailand Research Fund/Chulalongkorn University assume no responsibility for personal injury or property damage to users or third parties caused by the material.
Such users assume all risks associated with the use of the material.