HAZARD (UN) |
EXPOSURE CONTROLS/PERSONAL PROTECTION |
F+ | T |
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Extremely flammable. Toxic. SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT May cause cancer. Extremely flammable. May form explosive peroxides. Also harmful by inhalation and if swallowed. Irritating to skin. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Also possible risks of irreversible effects. Carc. Cat.2 Muta. Cat.3 |
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ENGINEERING CONTROLS Safety shower and eye bath. Use nonsparking tools. Mechanical exhaust required. GENERAL HYGIENE MEASURES Remove and wash contaminated clothing promptly. Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Government approved respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. |
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HANDLING Directions for Safe Handling: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep container closed. Keep away from heat, sparks, and open flame. SPECIAL REQUIREMENTS: Refrigerate before opening. May develop pressure. Open carefully. |
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PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. Use nonsparking tools. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. |
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EXTINGUISHING MEDIA Suitable: Carbon dioxide, dry chemical powder, or appropriate foam. Unsuitable: Water may be effective for cooling, but may not effect extinguishment. SPECIAL RISKS Specific Hazard(s): Extremely flammable. Vapor may travel considerable distance to source of ignition and flash back. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air. Caution: forms explosive peroxides on prolonged storage. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SPECIFIC METHOD(S) OF FIRE FIGHTING Use water spray to cool fire-exposed containers. |
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AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of contact, immediately wash skin with soap and copious amounts of water. AFTER EYE CONTACT In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. |