Safety data sheet
According to EC Directive 91/155/EEC
MERCK
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1. Identification of the substance/preparation and of the company/undertaking
Identification of the product
Catalogue No.: 100564
Product name: ortho-Phosphoric acid 89% extra pure DAB,Ph Eur,BP

Manufacturer/supplier identification
Company: Merck Ltd.
9th Floor, Monterey Tower, 2170 New Petchburi Road, Bangkapi, Huaykwang, Bangkok 10320
Tel: (662) 308 - 0218

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2. Composition/information on ingredients
Aqueous solution.

Synonyms
Orthophosphoric acid

CAS-No.: 7664-38-2 EC-Index-No.: -
Molar mass: 98.00 EINECS-No.: 231-633-2
Molecular formula: H3PO4

Hazardous ingredients:
Name according to EC Directives: Phosphoric acid
Hazard symbols: C R-phrases: 34
EC-Index-No.: 015-011-00-6 Causes burns.
CAS-No..: 7664-38-2 Content: 89%

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3. Hazards identification
Causes burns.

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4. First aid measures
After inhalation: fresh air. Summon doctor.
After skin contact: wash off with plenty of water. Dab with polyethylene glycol 400. Immediately remove contaminated clothing.
After eye contact: rinse out with plenty of water for at least 10 minutes with the eyelid held wide open. Immediately summon eye specialist.
After swallowing: make victim drink plenty of water (if necessary several litres), avoid vomiting (risk of perforation!). Immediately summon doctor. Do not attempt to neutralize.

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5. Fire-fighting measures
Suitable extinguishing media:
In adaption to materials stored in the immediate neighbourhood.

Special risks:
Non-combustible. Hydrogen may form upon contact with metals (danger of explosion!).

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6. Accidental release measures
Person-related precautionary measures:
Avoid substance contact.

Environmental-protection measures:
Do not allow to enter sewerage system.

Procedures for cleaning / absorption:
Render harmless: neutralize with diluted sodium hydroxide solution or by throwing on lime, lime sand, or sodium carbonate. Take up with liquid-absorbent material (e.g. Chemizorb ). Forward for disposal. Clean up affected area.

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7. Handling and storage
Handling:
No further requirements.

Storage:
Tightly closed. Dry. At +15C to +25C.

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8. Exposure controls/personal protection
Personal protective equipment:
Respiratory protection: required when vapours/aerosols are generated.
Eye protection: required
Hand protection: required
Other protective equipment: Suitable protective clothing.
Industrial hygiene: Immediately change contaminated clothing. Apply skin- protective barrier cream. Wash hands and face after working with substance.

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9. Physical and chemical properties
Form: liquid
Colour: colourless
Odour: odourless
pH value
at 100 g/l water (20 C) < 0.5
Melting temperature ҳ 25 C
Boiling temperature ~ 160 C
Ignition temperature not available
Flash point not available
Explosion limits lower not available
upper not available
Vapour pressure (25 C) 2.5 mbar
Density (20 C) 1.75 g/cm3
Solubility in water (20 C) soluble

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10. Stability and reactivity
Conditions to be avoided
Strong heating.

Substances to be avoided
metallic oxides , bases metals Formation of: hydrogen

Hazardous decomposition products
phosphorus oxide

Further information
hygroscopic ; incompatible with iron/iron-containing compounds , steel , aluminium and their compounds

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11. Toxicological information
Acute toxicity
LD50 (oral, rat): 1530 mg/kg ;
LD50 (dermal, rabbit): 2740 mg/kg

Further toxicological information
After inhalation of vapours: Irritation symptoms in the respiratory tract.
After skin contact: irritant and caustic effects
After eye contact: Burns. Risk of blindness!
After swallowing: burns , strong pain (risk of perforation!)
Systemic effects: shock , spasms

Further data
The product should be handled with the care usual when dealing with chemicals.

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12. Ecological information
Ecotoxicity effects:
Biological effects: Toxic for aquatic organisms. aquatic organisms LC50: 100 mg/l /96 h
Caustic even in diluted form. Harmful effect due to pH shift. Depending on the concentration, phosphorus compounds may contribute to the eutrophication of water supplies.
Further ecologic data:
Do not allow to enter waters, waste water, or soil!

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13. Disposal considerations
Product:
There are no uniform EC Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste.

Packaging:
Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminated packaging may be treated like household waste or recycled.

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14. Transport information
Transport over land ADR/RID and GGVS/GGVE (Germany)
GGVS/GGVE class: 8 Number and letter: 17c
ADR/RID class: 8 Number and letter: 17c
Name of material: 1805 PHOSPHORSAEURE

River transport ADN/ADNR
not examined

Sea transport IMDG
IMDG class: 8 UN-No.: 1805 Packaging group: III
Ems: 8-08 MFAG: 700
Correct technical name: ORTHOPHOSPHORIC ACID, LIQUID

Air transport ICAO-TI and IATA-DGR
ICAO/IATA class: 8 UN/ID-No.: 1805 Packaging group: III
Correct technical name: PHOSPHORIC ACID

The transport regulations are cited according to international regulations and in the form applicable in Germany (GGVS/GGVE). Possible national deviations in other countries are not considered.

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15. Regulatory information
Labelling according to EC Directives
Symbol: C Corrosive immediately and show this container or label.
R-phrases: R 34 Causes burns.
S-phrases: S 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
EC-No.: 231-633-2 EC label

German regulations
Water pollution class 1 (slightly polluting substance)

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16. Other information
Reason for alteration
Change in labelling.

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