Safety data sheet
According to EC Directive 91/155/EEC
MERCK Schuchardt
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1. Identification of the substance/preparation and of the company/undertaking
Identification of the product
Catalogue No.: 801554
Product name: Ethylene glycol monobutyl ether for synthesis

Manufacturer/supplier identification
Company: Merck Ltd.
9th Floor, Monterey Tower, 2170 New Petchburi Road, Bangkapi, Huaykwang, Bangkok 10320
Tel: (662) 308 - 0218

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2. Composition/information on ingredients
Synonyms
2-Butoxyethanol ; Butyl glycol

CAS-No.: 111-76-2 EC-Index-No.: 603-014-00-0
Molar mass: 118.18 EINECS-No.: 203-905-0
Molecular formula: C6H14O2

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3. Hazards identification
Harmful by inhalation, in contact with skin and if swallowed. Irritating to respiratory system.

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4. First aid measures
After inhalation: fresh air.
After skin contact: wash off with plenty of water. Remove contaminated clothing.
After eye contact: rinse out with plenty of water with the eyelid held wide open.
After swallowing: make victim drink plenty of water, induce vomiting, summon doctor.

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5. Fire-fighting measures
Suitable extinguishing media:
Water, CO2, foam, powder.

Special risks:
Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Special protective equipment for fire fighting:
Do not stay in dangerous zone without self-contained breathing apparatus.

Other information:
Prevent fire-fighting water from entering surface water or groundwater.

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6. Accidental release measures
Person-related precautionary measures:
Do not inhale vapours/aerosols. Ensure supply of fresh air in enclosed rooms.
Environmental-protection measures:
Do not allow to enter sewerage system.
Procedures for cleaning / absorption:
Take up with liquid-absorbent material (e.g. Chemizorb ). Forward for disposal. Clean up affected area.

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7. Handling and storage
Handling:
protected from light

Storage:
At +15C to +25C. Tightly closed. No further requirements.

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8. Exposure controls/personal protection
Specific control parameter
MAK Germany (max. workplace conc.)
Ethylene glycol monobutyl ether 20 ml/m3 or 98 mg/m3

Personal protective equipment:
Respiratory protection: required when vapours/aerosols are generated.
Eye protection: required
Hand protection: required
Industrial hygiene: Change contaminated clothing. Application of skin-protective barrier cream recommended. Wash hands and face after working with substance.

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9. Physical and chemical properties
Form: liquid
Colour: colourless
Odour: slightly etheral
pH value ( ) 7
Viscosity dynamic (20 C) 5.31 mPa*s
Melting temperature -70 C
Boiling temperature 170 - 172 C
Ignition temperature 230 C
Flash point 50 C
Explosion limits lower 1.9 Vol%
upper 10.3 Vol%
Vapour pressure (20 C) 0.8 hPa
Density (20 C) 0.90 g/cm3
Solubility in water (20 C) soluble
organic solvents (20 C) soluble

Further information
Distillable in an undecomposed state at normal pressure.

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10. Stability and reactivity
no information available

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11. Toxicological information
Acute toxicity
LD50 (oral, rat): 1480 mg/kg
LD50 (dermal, rabbit): 490 mg/kg

Subacute to chronic toxicity
An embryotoxic effect need not be feared when the threshold limit value is observed.

Further toxicological information
After inhalation: Irritations of the mucous membranes, coughing, and dyspnoea.
After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.
Danger of skin absorption.

Further data
Further hazardous properties cannot be excluded.
The product should be handled with the care usual when dealing with chemicals.

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12. Ecological information
Ecotoxic effects:
fish LC0: > 1000 mg/l
bacteria EC0: > 1000 mg/l
Further ecologic data:
No ecological problems are to be expected when the product is handled and used with due care and attention.

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13. Disposal considerations
Product:
There are no uniform EC Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste.

Packaging:
Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminated packaging may be treated like household waste or recycled.

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14. Transport information
Not subject to transport regulations.

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15. Regulatory information
Labelling according to EC Directives
Symbol: Xn Harmful immediately and show this container or label.
R-phrases: R 20/21/22-37 Harmful by inhalation, in contact with skin and if swallowed. Irritating to respiratory system.
S-phrases: S 24/25 Avoid contact with skin and eyes.
EC-No.: 203-905-0 EC label

German regulations
Water pollution class 1 (slightly polluting substance)

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16. Other information
Reason for alteration
Change in transport classification.
General update.

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