4-PICOLINE, 99%
Synonym:
  Synonyms * Ba 35846 * p-Methylpyridine * 4-Methylpyridine * gamma-Picoline * p-Picoline * 4-Picoline (8CI)
CAS Number : 108-89-4
HAZARD (UN)
EXPOSURE CONTROLS/PERSONAL PROTECTION

T
Toxic.
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
     Flammable.  Harmful by inhalation and if swallowed.  Toxic in contact with skin.  Irritating to eyes, respiratory system and skin.
ENGINEERING CONTROLS
     Use only in a chemical fume hood.  Safety shower and eye bath.
GENERAL HYGIENE MEASURES
     Wash contaminated clothing before reuse.  Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Special Protective Measures:  Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
HANDLING
     Directions for Safe Handling:  Avoid contact and inhalation.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Keep away from heat and open flame.  Store in a cool dry place.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.  Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Cover with dry-lime, sand, or soda ash.  Place in covered containers using non-sparking tools and transport outdoors.
EXTINGUISHING MEDIA
     Suitable:  Carbon dioxide, dry chemical powder, or appropriate foam.
SPECIAL RISKS
     Specific Hazard(s):  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Forms explosive mixtures in air.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER EYE CONTACT
     Assure adequate flushing of the eyes by separating the eyelids with fingers.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #239615

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Such users assume all risks associated with the use of the material.