HAZARD (UN) |
EXPOSURE CONTROLS/PERSONAL PROTECTION |
T |
|
Toxic. SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Flammable. Reacts violently with water. Harmful by inhalation and if swallowed. Causes severe burns. Toxic: danger of serious damage to health by prolonged exposure through inhalation. |
|
ENGINEERING CONTROLS Safety shower and eye bath. Use only in a chemical fume hood. GENERAL HYGIENE MEASURES Wash contaminated clothing before reuse. Discard contaminated shoes. Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Government approved respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. Special Protective Measures: Faceshield (8-inch minimum). |
|
HANDLING Directions for Safe Handling: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, sparks, and open flame. Store under nitrogen. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS: Store under inert gas. |
|
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry lime or soda ash, pick up, keep in a closed container, and hold for waste disposal. Ventilate area and wash spill site after material pickup is complete. |
|
EXTINGUISHING MEDIA Suitable: Dry chemical powder. Carbon dioxide. Unsuitable: Do not use water. SPECIAL RISKS Specific Hazard(s): Combustible liquid. Emits toxic fumes under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. CONDITIONS OF FLAMMABILITY Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. |
|
AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. Do not induce vomiting. |