CARBON DIOXIDE, PRESSURE TIN WITH 1 L
Synonym:
  Synonyms * Anhydride carbonique (French) * Carbon dioxide (ACGIH:OSHA) * Carbonic acid anhydride * Carbonic acid gas * Carbonic anhydride * Carbon oxide * Dry ice * Khladon 744 * Kohlendioxyd (German) * Kohlensaure (German) * R 744
CAS Number : 124-38-9
HAZARD (UN)
EXPOSURE CONTROLS/PERSONAL PROTECTION
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
     Not hazardous according to Directive 67/548/EC.
ENGINEERING CONTROLS
     Mechanical exhaust required.  Safety shower and eye bath.
GENERAL HYGIENE MEASURES
     Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection:  Government approved respirator in nonventilated areas and/or for exposure above the TLV or PEL.
     Hand Protection:  Compatible chemical-resistant gloves.
     Eye Protection:  Chemical safety goggles.
WORK PRACTICES
     Store and use with adequate ventilation.
HANDLING
     Directions for Safe Handling:  Do not breathe gas.  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Cylinder temperature should not exceed 125?F (52?C).
SPECIAL REQUIREMENTS:
     Contents under pressure.  Do not heat above 50?C.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area and keep personnel upwind.  Shut off leak if there is no risk.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Ventilate area and wash spill site after material pickup is complete.
EXTINGUISHING MEDIA
     Suitable:  Use water spray or fog nozzle to keep cylinder cool.  Move cylinder away from fire if there is no risk.
SPECIAL RISKS
     Specific Hazard(s):  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Container explosion may occur under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
     In case of contact, immediately wash skin with soap and copious amounts of water.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.  Assure adequate flushing by separating the eyelids with fingers.  Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #00486

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