HAZARD (GHS) |
EXPOSURE CONTROLS/PERSONAL PROTECTION |
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Extremely flammable liquid and vapour / There are no lebel elements allocated to this category / Fetal if swallowed / Fetal if contact with skin / Cause skin irritation / Cause serious eye irritation / Suspected of causing cancer / Suspected of damaging fertility or the unborn child / Cause damage to organ (blood, nervous system, hematopoietic system, liver, kidney, respiratory, adrenal) / Toxic to aquatic life / Toxic to aquatic life with long lasting effects |
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ENGINEERING CONTROLS Safety shower and eye bath. Use nonsparking tools. Use only in a chemical fume hood. GENERAL HYGIENE MEASURES Wash contaminated clothing before reuse. Discard contaminated shoes. Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Government approved respirator. Hand Protection: Compatible chemical-resistant gloves. Rubber gloves. Eye Protection: Chemical safety goggles. Special Protective Measures: Faceshield (8-inch minimum). |
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HANDLING Directions for Safe Handling: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Store in a cool dry place. Keep away from heat, sparks, and open flame. Handle and store under nitrogen. SPECIAL REQUIREMENTS: Air sensitive. Hygroscopic. |
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PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. Use nonsparking tools. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. |
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EXTINGUISHING MEDIA Suitable: Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Flammable liquid. Emits toxic fumes under fire conditions. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. CONDITIONS OF FLAMMABILITY Under fire conditions, material may decompose to form flammable and/or explosive mixtures in air. Warning: hydrazine vapor in air is flammable at 4.7 to 100% hydrazine by volume - handle under nitrogen! Some metals and alloys including monel, bronze, brass, cadmium, gold, molybdenum, and stainless steel with more than 0.5% molybdenum or rust cause decomposition of hydrazine |
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AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. Do not induce vomiting. |