1,1-DICHLOROETHENE, STANDARD FOR GC, STAB.
Synonym:
  Synonyms * Chlorure de vinylidene (French) * 1,1-Dichloroethene (9CI) * 1,1-Dichloroethylene * Ethene, 1,1-dichloro- * NCI-C54262 * RCRA waste number U078 * VDC * Vinylidene chloride * Vinylidene chloride (II) * Vinylidene chloride (ACGIH) * Vinylidene dichloride * Vinylidine chloride
CAS Number : 75-35-4
HAZARD (GHS)
EXPOSURE CONTROLS/PERSONAL PROTECTION
Extremely flammable liquid and vapour / Harmful if swallowed / Toxic if swallowed / Suspected of damaging fertility or the unborn child / Cause damage to organ (liver, kidney, respiratory) / May cause respiratory irritation; or may cause drowsiness or dizziness / May cause damage to organs (kidney) / May be harmful if swallowed and enter airways / harmful to aquatic life
ENGINEERING CONTROLS
     Safety shower and eye bath.  Use nonsparking tools.  Use only in a chemical fume hood.  Mechanical exhaust required.
GENERAL HYGIENE MEASURES
     Wash contaminated clothing before reuse.  Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection:  Government approved respirator.
     Hand Protection:  Compatible chemical-resistant gloves.
     Eye Protection:  Chemical safety goggles.
HANDLING
     Directions for Safe Handling:  Do not breathe vapor.  Avoid contact with eyes, skin, and clothing.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep container closed.  Keep away from heat, sparks, and open flame.  May form peroxides on prolonged storage.  Date container and periodically test for peroxides.  Store at 2-8?C
SPECIAL REQUIREMENTS:
     Air and moisture sensitive.  Store under inert gas.  May develop pressure.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.  Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Cover with dry-lime, sand, or soda ash.  Place in covered containers using non-sparking tools and transport outdoors.  Ventilate area and wash spill site after material pickup is complete.
ENVIRONMENTAL PRECAUTION(S)
     Avoid contaminating sewers and waterways with this material.  Avoid contaminating water supply.
EXTINGUISHING MEDIA
     Suitable:  Carbon dioxide, dry chemical powder, or appropriate foam.
     Unsuitable:  Do not direct a solid stream of water or foam into burning molten material; this may cause spattering and spread the fire.
SPECIAL RISKS
     Specific Hazard(s):  Vapor may travel considerable distance to source of ignition and flash back.  Extremely flammable.  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Container explosion may occur under fire conditions.  Vapor may travel considerable distance to source of ignition and flash back.  Forms explosive mixtures in air.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
     In case of skin contact, flush with copious amounts of water for at least 15 minutes.  Remove contaminated clothing and shoes.  Call a physician.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.  Assure adequate flushing by separating the eyelids with fingers.  Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician immediately.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529, Catalog #02574

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Such users assume all risks associated with the use of the material.