AMMONIA, ANHYDROUS, 99.99+%
Synonym:
  Synonyms * AM-Fol * Ammonia (ACGIH:OSHA) * Ammonia anhydrous * Ammoniac (French) * Ammoniaca (Italian) * Ammonia gas * Ammoniak (German) * Amoniak (Polish) * Nitro-sil * R 717 * Spirit of hartshorn
CAS Number : 7664-41-7
HAZARD (GHS)
EXPOSURE CONTROLS/PERSONAL PROTECTION
Extreamly flammable gas / Contains gas under pressure; may explode if heated / Harmful if inhaled / Cause serious eye damage / May cause allergy or asthma symptoms or breathing difficulties if inhaled / Suspected of causing genetic defects / Cause damage to organ (respiratory system) / May cause damage to organs (lung) / Very toxic to aquatic life / very toxic to aquatic life with long lasting effects
ENGINEERING CONTROLS
     Safety shower and eye bath.
     Warning:  suck-back into cylinder may cause rupture.  Use back-flow-preventive device in piping.  Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
     Discard contaminated clothing and shoes.  Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
     Respiratory Protection:  Government approved respirator in nonventilated areas and/or for exposure above the TLV or PEL.
     Hand Protection:  Compatible chemical-resistant gloves.
     Eye Protection:  Chemical safety goggles.
     Special Protective Measures:  Faceshield (8-inch minimum).
HANDLING
     Directions for Safe Handling:  Do not breathe gas.  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Use with equipment rated for cylinder pressure, and of compatible materials of construction.  Close valve when not in use and when empty.  Make sure cylinder is properly secured when in use or stored Cylinder temperature should not exceed 125?F (52?C).
SPECIAL REQUIREMENTS:
     Contents under pressure.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area and keep personnel upwind.  Shut off leak if there is no risk.  Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Ventilate area and wash spill site after material pickup is complete.
EXTINGUISHING MEDIA
     Suitable:  Use water spray or fog nozzle to keep cylinder cool.  Move cylinder away from fire if there is no risk.
SPECIAL RISKS
     Specific Hazard(s):  Vapor may travel considerable distance to source of ignition and flash back.  Emits toxic fumes under fire conditions.  Flammable gas.
     Explosion Hazards:  May form explosive mixtures with air Container explosion may occur under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
     Do not extinguish burning gas if flow cannot be shut off immediately.  Use water spray or fog nozzle to keep cylinder cool.  Move cylinder away from fire if there is no risk.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
     In case of contact, immediately wash skin with soap and copious amounts of water.
AFTER EYE CONTACT
     Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water.  Assure adequate flushing of the eyes by separating the eyelids with fingers.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529, Catalog #294993

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