HAZARD (GHS) |
EXPOSURE CONTROLS/PERSONAL PROTECTION |
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Extreamly flammable gas / Contains gas under pressure; may explode if heated / Harmful if inhaled / Cause serious eye damage / May cause allergy or asthma symptoms or breathing difficulties if inhaled / Suspected of causing genetic defects / Cause damage to organ (respiratory system) / May cause damage to organs (lung) / Very toxic to aquatic life / very toxic to aquatic life with long lasting effects |
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ENGINEERING CONTROLS Safety shower and eye bath. Warning: suck-back into cylinder may cause rupture. Use back-flow-preventive device in piping. Use only in a chemical fume hood. GENERAL HYGIENE MEASURES Discard contaminated clothing and shoes. Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Government approved respirator in nonventilated areas and/or for exposure above the TLV or PEL. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. Special Protective Measures: Faceshield (8-inch minimum). |
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HANDLING Directions for Safe Handling: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Use with equipment rated for cylinder pressure, and of compatible materials of construction. Close valve when not in use and when empty. Make sure cylinder is properly secured when in use or stored Cylinder temperature should not exceed 125?F (52?C). SPECIAL REQUIREMENTS: Contents under pressure. |
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PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area and keep personnel upwind. Shut off leak if there is no risk. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Ventilate area and wash spill site after material pickup is complete. |
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EXTINGUISHING MEDIA Suitable: Use water spray or fog nozzle to keep cylinder cool. Move cylinder away from fire if there is no risk. SPECIAL RISKS Specific Hazard(s): Vapor may travel considerable distance to source of ignition and flash back. Emits toxic fumes under fire conditions. Flammable gas. Explosion Hazards: May form explosive mixtures with air Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SPECIFIC METHOD(S) OF FIRE FIGHTING Do not extinguish burning gas if flow cannot be shut off immediately. Use water spray or fog nozzle to keep cylinder cool. Move cylinder away from fire if there is no risk. |
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AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of contact, immediately wash skin with soap and copious amounts of water. AFTER EYE CONTACT Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water. Assure adequate flushing of the eyes by separating the eyelids with fingers. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. |