METHYL CHLOROFORMATE, 99%
Synonym:
  Synonyms * Chlorameisensaeure methylester (German) * Chlorocarbonate de methyle (French) * Chlorocarbonic acid methyl ester * Chloroformiate de methyle (French) * Chloroformic acid methyl ester * Formic acid, chloro-, methyl ester * MCF * Methoxycarbonyl chloride * Methylchloorformiaat (Dutch) * Methyl chlorocarbonate * Methylester kyseliny chlormravenci (Czech) * Methylester kyseliny chloruhlicite (Czech) * Metilcloroformiato (Italian) * RCRA waste number U156 * TL 438
CAS Number : 79-22-1
HAZARD (UN)
EXPOSURE CONTROLS/PERSONAL PROTECTION

F

T
Highly flammable.
Toxic.
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
     Highly flammable.  Toxic by inhalation.  Irritating to eyes, respiratory system and skin.
ENGINEERING CONTROLS
     Use only in a chemical fume hood.  Safety shower and eye bath.  Use nonsparking tools.
GENERAL HYGIENE MEASURES
     Wash thoroughly after handling.  Discard contaminated shoes.
PERSONAL PROTECTIVE EQUIPMENT
     Eye Protection:  Use safety shield.
     Special Protective Measures:  Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
HANDLING
     Directions for Safe Handling:  Do not breathe vapor.  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.  Open carefully.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Keep away from heat, sparks, and open flame.  Refrigerate on arrival.  Store at 2-8?C
SPECIAL REQUIREMENTS:
     Vent periodically.  May develop pressure.  Open carefully.  Moisture sensitive.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.  Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Absorb on sand or vermiculite and place in closed containers for disposal.
EXTINGUISHING MEDIA
     Suitable:  Carbon dioxide, dry chemical powder, or appropriate foam.
     Unsuitable:  Do not use water.
SPECIAL RISKS
     Specific Hazard(s):  Flammable liquid.  Vapor may travel considerable distance to source of ignition and flash back.  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Vapor may travel considerable distance to source of ignition and flash back.  Container explosion may occur under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
     Use water spray to cool fire-exposed containers.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER EYE CONTACT
     Assure adequate flushing of the eyes by separating the eyelids with fingers.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #M35304

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However,no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof.
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Such users assume all risks associated with the use of the material.