GUIDE 167 FLUORINE (Refrigerated Liquid)

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POTENTIAL HAZARDS
HEALTH
- TOXIC; may be fatal if inhaled.
- Vapors are extremely irritating.
- Contact with gas or liquefied gas will cause burns, severe injury and/or frostbite.
- Vapors from liquefied gas are initially heavier than air and spread along ground.
- Runoff from fire control may cause pollution.
FIRE OR EXPLOSION
- Substance does not burn but will support combustion.
- This is a strong oxidizer and will react vigorously or explosively with many materials including fuels.
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Vapor explosion and poison hazard indoors, outdoors or in sewers.
- Containers may explode when heated.
- Ruptured cylinders may rocket.
PUBLIC SAFETY
- CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
- As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions.
- Keep unauthorized personnel away.
- Stay upwind.
- Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks).
- Keep out of low areas.
- Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
- Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.
- Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.
EVACUATION
Spill
- See Table 1 - Initial Isolation and Protective Action Distances.
Fire
- If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.
EMERGENCY RESPONSE
FIRE
Small Fire
- Dry chemical, soda ash, lime or sand.
Large Fire
- Water spray, fog (flooding amounts).
- Do not get water inside containers.
- Move containers from fire area if you can do it without risk.
Fire involving Tanks
- Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
- Cool containers with flooding quantities of water until well after fire is out.
- Do not direct water at source of leak or safety devices; icing may occur.
- Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
- ALWAYS stay away from tanks engulfed in fire.
- For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
SPILL OR LEAK
- Do not touch or walk through spilled material.
- If you have not donned special protective clothing approved for this material, do not expose yourself to any risk of this material touching you.
- Do not direct water at spill or source of leak.
- A fine water spray remotely directed to the edge of the spill pool can be used to direct and maintain a hot flare fire that will burn the spilled material in a controlled manner.
- Keep combustibles (wood, paper, oil, etc.) away from spilled material.
- Stop leak if you can do it without risk.
- Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.
- If possible, turn leaking containers so that gas escapes rather than liquid.
- Prevent entry into waterways, sewers, basements or confined areas.
- Isolate area until gas has dispersed.
- Ventilate the area.
FIRST AID
- Move victim to fresh air.
- Call 911 or emergency medical service.
- Give artificial respiration if victim is not breathing.
- Administer oxygen if breathing is difficult.
- Clothing frozen to the skin should be thawed before being removed.
- Remove and isolate contaminated clothing and shoes.
- In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
- Keep victim warm and quiet.
- Keep victim under observation.
- Effects of contact or inhalation may be delayed.
- Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.