GUIDE 169 Aluminum (Molten)

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POTENTIAL HAZARDS
FIRE OR EXPLOSION
- Substance is transported in molten form at a temperature above 705°C (1300°F).
- Violent reaction with water; contact may cause an explosion or may produce a flammable gas.
- Will ignite combustible materials (wood, paper, oil, debris, etc.).
- Contact with nitrates or other oxidizers may cause an explosion.
- Contact with containers or other materials, including cold, wet or dirty tools, may cause an explosion.
- Contact with concrete will cause spalling and small pops.
HEALTH
- Contact causes severe burns to skin and eyes.
- Fire may produce irritating and/or toxic gases.
PUBLIC SAFETY
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
- Stay upwind, uphill and/or upstream.
- Keep unauthorized personnel away.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
PROTECTIVE CLOTHING
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Wear flame-retardant structural firefighters' protective clothing, including faceshield, helmet and gloves, as this will provide limited thermal protection.
EVACUATION
Immediate precautionary measure
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
EMERGENCY RESPONSE
FIRE
- Do not use water, except in life-threatening situations and then only in a fine spray.
- Do not use halogenated extinguishing agents or foam.
- Move combustibles out of path of advancing pool if you can do so without risk.
- Extinguish fires started by molten material by using appropriate method for the burning material; keep water, halogenated extinguishing agents and foam away from the molten material.
SPILL OR LEAK
- Do not touch or walk through spilled material.
- Do not attempt to stop leak, due to danger of explosion.
- Keep combustibles (wood, paper, oil, etc.) away from spilled material.
- Substance is very fluid, spreads quickly, and may splash. Do not try to stop it with shovels or other objects.
- Dike far ahead of spill; use dry sand to contain the flow of material.
- Where possible allow molten material to solidify naturally.
- Avoid contact even after material solidifies. Molten, heated and cold aluminum look alike; do not touch unless you know it is cold.
- Clean up under the supervision of an expert after material has solidified.
FIRST AID
- Call 911 or emergency medical service.
- Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.
- Move victim to fresh air if it can be done safely.
- Give artificial respiration if victim is not breathing.
- Administer oxygen if breathing is difficult.
- For severe burns, immediate medical attention is required.
- Removal of solidified molten material from skin requires medical assistance.
- Remove and isolate contaminated clothing and shoes.
- In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
- Keep victim calm and warm.