THIOPHOSGENE, 97%
Synonym:
  Synonyms * Carbon chlorosulfide * Carbonothioic dichloride (9CI) * Carbonyl chloride, thio- * Dichlorothiocarbonyl * Phosgene, thio- * Thiocarbonic dichloride * Thiocarbonyl chloride * Thiocarbonyl dichloride * Thiofosgen (Czech) * Thiokarbonylchlorid (Czech)
CAS Number : 463-71-8
HAZARD (UN)
EXPOSURE CONTROLS/PERSONAL PROTECTION

T
Toxic.
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
     Harmful if swallowed.  Toxic by inhalation.  Irritating to eyes, respiratory system and skin.
ENGINEERING CONTROLS
     Safety shower and eye bath.  Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
     Wash thoroughly after handling.  Wash contaminated clothing before reuse.
PERSONAL PROTECTIVE EQUIPMENT
     Special Protective Measures:  Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
HANDLING
     Directions for Safe Handling:  Do not breathe vapor.  Do not get in eyes, on skin, on clothing.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Store under nitrogen.  Store at 2-8?C
SPECIAL REQUIREMENTS:
     Moisture sensitive.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
     Absorb on sand or vermiculite and place in closed containers for disposal.
EXTINGUISHING MEDIA
     Unsuitable:  Do not use water.
SPECIAL RISKS
     Specific Hazard(s):  Emits toxic fumes under fire conditions.
     Explosion Hazards:  Container explosion may occur under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
CONDITIONS OF FLAMMABILITY
     Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529, Catalog #115150

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