TOLYLENE-2,4-DIISOCYANATE FOR ELECTRON MICROSCOPY
Synonym:
  Synonyms * Cresorcinol diisocyanate * Desmodur T80 * Di-isocyanate de toluylene (French) * Di-iso-cyanatoluene * 2,4-Diisocyanato-1-methylbenzene (9CI) * 2,4-Diisocyanatotoluene * Diisocyanat-toluol (German) * Hylene T * Isocyanic acid, 4-methyl-m-phenylene ester * 4-Methyl-phenylene diisocyanate * 4-Methyl-phenylene isocyanate * Mondur TD * Mondur TD-80 * Mondur TDS * Nacconate IOO * NCI-C50533 * RCRA waste number U223 * TDI * 2,4-TDI * TDI-80 * TDI (OSHA) * Tolueen-diisocyanaat (Dutch) * Toluen-disocianato (Italian) * Toluene diisocyanate * Toluene-2,4-diisocyanate * 2,4-Toluenediisocyanate * Toluene-2,4-diisocyanate (ACGIH:OSHA) * Toluilenodwuizocyjanian (Polish) * Tuluylendiisocyanat (German) * Toluylene-2,4-diisocyanate * Tolyene 2,4-diisocyanate * Tolylene-2,4-diisocyanate * 2,4-Tolylenediisocyanate
CAS Number : 584-84-9
HAZARD (GHS)
EXPOSURE CONTROLS/PERSONAL PROTECTION
Harmful if inhaled / Cause skin irritation / May cause allergy or asthma symptoms or breathing difficulties if inhaled / May cause an allergic skin reaction / Suspected of causing cancer / May cause damage to organs (respiratory) / Cause damage to organ (respiratory, hematopoietic system)
ENGINEERING CONTROLS
     Safety shower and eye bath.  Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
     Wash thoroughly after handling.  Wash contaminated clothing before reuse.
PERSONAL PROTECTIVE EQUIPMENT
     Special Protective Measures:  Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.  Faceshield (8-inch minimum).
HANDLING
     Directions for Safe Handling:  Do not get in eyes, on skin, on clothing.  Avoid prolonged or repeated exposure.  Do not breathe vapor.
STORAGE
     Conditions of Storage:  Keep tightly closed.  Store under nitrogen.
SPECIAL REQUIREMENTS:
     Store under inert gas.  Light and moisture sensitive.

FIRE FIGHTING MEASURES

FIRST-AID MEASURES

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
     Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
     Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.  Wear disposable coveralls and discard them after use.
METHODS FOR CLEANING UP
     Cover with an activated carbon adsorbent, take up and place in closed containers.  Transport outdoors.  Ventilate area and wash spill site after material pickup is complete.
EXTINGUISHING MEDIA
     Suitable:  Carbon dioxide.  Dry chemical powder.
SPECIAL RISKS
     Specific Hazard(s):  Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
     Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
AFTER INHALATION
     If inhaled, remove to fresh air.  If not breathing give artificial respiration.  If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
     In case of skin contact, flush with copious amounts of water for at least 15 minutes.  Remove contaminated clothing and shoes.  Call a physician.
AFTER EYE CONTACT
     In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.  Assure adequate flushing by separating the eyelids with fingers.  Call a physician.
AFTER INGESTION
     If swallowed, wash out mouth with water provided person is conscious.  Call a physician immediately.
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Reference: Sigma-Aldrich Pte Ltd #08-01 Citilink Warehouse Singapore 118529 Singapore, Catalog #89870

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